The Importance of Being Exchanged: [GdIII4MII8(OH)8(L)8(O2CR)8]4+Clusters for Magnetic Refrigeration

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The Importance of Being Exchanged: [Gd4M8(OH)8(L)8(O2CR)8] Clusters for Magnetic Refrigeration

One of the most promising applications for molecules built from paramagnetic metal ions is low temperature magnetic refrigeration.[1] Indeed recent studies have suggested that molecular coolers can outperform any conventionally-employed solid-state refrigerant material by orders of magnitude.[2] In order to do so, molecules must possess a combination of a large spin ground state (S), with negli...

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The importance of being exchanged: [Gd(III)4M(II)8(OH)8(L)8(O2CR)8]4+ clusters for magnetic refrigeration.

One of the most promising applications for molecules built from paramagnetic metal ions is low-temperature magnetic refrigeration. Indeed, recent studies have suggested that molecular coolers can outperform any conventionally employed solid-state refrigerant material by orders of magnitude. In order to do so, molecules must possess a combination of a large spin ground state (S), with negligible...

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ژورنال

عنوان ژورنال: Angewandte Chemie

سال: 2012

ISSN: 0044-8249

DOI: 10.1002/ange.201200072